Determining Pesticides in Dietary Supplements with QuEChERS Extraction, Cartridge SPE, and GCxGC-TOFMS
The novel approach used here combines QuEChERS extraction, cartridge SPE cleanup, and GCxGC-TOFMS analysis, resulting in good recoveries for a wide range of pesticides in dietary supplements. Matrices include dandelion root, sage, and a multi-herb finished product.
QuEChERS is a simple, effective approach to sample prep that can be applied to the analysis of pesticides in dietary supplements. Here, we demonstrate a QuEChERS, cSPE, GC-TOFMS procedure that results in good recoveries for a wide range of pesticides in dandelion root. (PDF - 0kB)
Evaluation of Dispersive and Cartridge Solid Phase Extraction (SPE) Cleanups for Multiresidue Pesticides in QuEChERS Extracts of Finished Tobacco Using GCxGC-TOFMS
We compared the efficacy of dSPE and cSPE cleanup methods for multiresidue pesticide analysis of QuEChERS extracts of finished tobacco products using GCxGC-TOFMS. Cleanup with dSPE tubes containing 7.5 mg of GCB and 25 mg of PSA produced better results than other methods, with average recoveries of 92% and 91% for 500 ppb and 50 ppb fortifications respectively.
Fast Screening of Recalled Tylenol for Tribromoanisole and Related Adulterants Using QuEChERS and GC-TOFMS
Screening methods for consumer product adulteration cases, such as the recent Tylenol recall, can benefit from fast QuEChERS-based sample preparation and sensitive, full mass-range GC/TOF-MS.
QuEChERS dSPE methods simplify extract cleanup, reduce material costs, and improve sample throughput. Here we demonstrate the effectiveness of QuEChERS sample cleanup using a multiresidue analysis of pesticides on strawberries. (PDF - 0kB)
Improve GC Analysis of Extractable Petroleum Hydrocarbons Using Resprep EPH Fractionation SPE Cartridges
New manufacturing and testing procedures for Resprep EPH fractionation SPE cartridges reduce background levels of extractable contaminants and assure more reliable fractionation of aliphatics from aromatics. (PDF - 0kB)
Ensure cleaner sample extracts and obtain high recoveries of target pesticides by adding a Resprep CarboPrep SPE cleanup step when preparing samples for chlorinated pesticides analysis. (PDF - 0kB)
Mitigating Matrix Effects: Examination of Dilution, QuEChERS, and Calibration Strategies for LC-MS/MS Analysis of Pesticide Residues in Diverse Food Types
LC-MS/MS is popular for monitoring pesticide residues in food due to its selectivity and sensitivity; however, matrix effects can cause poor data quality and difficult quantification. We evaluated the relative effectiveness of sample dilution, QuEChERS cleanup, solvent-based calibration, and matrix-matched calibration strategies to mitigate matrix effects in celery, kale, avocado, lime, and brown rice flour.
Prepare Olive Oil Samples for Pesticide Residue Analysis in Half the Time With a Fraction of the Solvent Using dSPE
Simplify and speed up sample preparation with Resprep dSPE tubes! Here we show the extraction and clean-up of pesticide residues from olive oil samples—twice as fast as GPC, with only a fraction of the solvent required for conventional SPE.
Restek offers a wide range of replacement parts and accessories—extraction cell parts, PEEK washers, collection vials, O-rings, filters, tools, and more!—for Accelerated Solvent Extraction (ASE) systems to keep them running smoothly. All parts are economically priced and designed to meet or exceed the performance of the original manufacturer’s parts. (PDF - 0kB)
Filtering sample extracts with syringe filters will greatly extend the life of costly chromatographic columns and replacement parts, particularly for HPLC systems. This 2-page fact sheet includes helpful membrane, porosity, and size selection guides. (PDF - 0kB)
Patented Thomson SINGLE StEP filter vials speed up sample preparation and analysis. The incorporated vial plunger contains an integrated membrane that filters samples with just one squeeze—a SINGLE StEP process to minimize sample loss while saving time and money during sample filtration. (PDF - 0kB)